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Identification of the Structural Boundary between [Ln(18-crown-6)(NO3)3] and [Ln(NO3)3(H2O)3] · 18-crown-6 Motifs in the Lanthanide Series

✍ Scribed by Cameron Jones; Peter C. Junk; Matthew K. Smith; Ryan C. Thomas

Publisher
John Wiley and Sons
Year
2000
Tongue
German
Weight
218 KB
Volume
626
Category
Article
ISSN
0372-7874

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✍ Florian Kraus; Tobias Hanauer; Nikolaus Korber 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 451 KB 👁 2 views

The bonding in the As 6 4À ion is studied in the unusually low-coordination environment provided by the compound {Rb[18]crown-6)} 2 Rb 2 As 6 •6 NH 3 . Theoretical analysis of the related P 6 4À ion indicates an unusual P¼P bond which contains major contributions from the lone pairs. Outside a highl