Structure of the complex [trans-SnF4(H2O)2· (18-crown-6)· 2H2O]
✍ Scribed by M. S. Fonar’; Yu. A. Simonov; G. Bogelly; é. V. Ganin; V. O. Gelmboldt
- Book ID
- 110632770
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1999
- Tongue
- English
- Weight
- 289 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0022-4766
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## Abstract Reaction of TiF~4~ and 18‐crown‐6 in MeCN affords the molecular complex [(__cis‐__TiF~4~)~2~(18‐crown‐6)] (1) only. Water and THF displace the 18‐crown‐6 in the tetrafluoro complex 1, with the formation of __cis‐__TiF~4~L~2~. The complex __cis‐__TiF~4~(H~2~O)~2~ and 18‐crown‐6 form [{__
A new nicotinamide complex of Fe(II) cation was prepared by reaction between ferrous sulfate and nicotinamide in aqueous solution. The complex was characterized on the basis of elemental analysis, FT IR and UV-VIS spectroscopy, electrochemistry (cyclic voltammetry) and X-ray crystallography. The com