Synthesis and Structure of Mo2NCl7.
✍ Scribed by Quang Thai Dinh; Markus Richter; Elke Niquet; Joachim Straehle
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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📜 SIMILAR VOLUMES
Inhaltsübersicht. Die Reaktion von VN mit MoCl 5 bei 175 °C in einer unter Vakuum abgeschmolzenen Glasampulle führt zur Bildung des Molybdän(V)nitridchlorids, Mo 2 NCl 7 in Form von luftempfindlichen, schwarz glänzenden, triklinen Kristallen mit der Raumgruppe P1 ¯und a ϭ 905,7(8); b ϭ 975,4(6); c ϭ
spectra. The broad resonance (8TMS= 37.6 ppm) observed at +27"C for C-10 and C-12 became a sharp singlet when the temperature was increased to +40°C and also when it was ~decreased to -20°C. At low temperatures no signal was Med. Chem. 6; 130 (1963) Table 2. Calculated strain energies of various con