Synthesis and Crystal Structure of (PPh4)3[Re2NCl10].
β Scribed by Simon Schwarz; Joachim Straehle
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 14 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
The reaction between PCl 3 and ReCl 5 yielded at 200 Β°C the ionic tetrachlorophosphonium dirhenium nonachloride, (PCl 4 )[Re 2 Cl 9 ]. Single crystal X-ray diffraction analysis revealed a monoclinic unit cell: a = 8.616(3) A Γ , b = 10.449(4) A Γ , c = 9.397(3) A Γ , b = 99.72(3)Β°, V = 833.9(5) A Γ
Hydrogen Diazide -Synthesis and Crystal Structure of PPh 4 [N 3 HN 3 ]. -The title compound (III) crystallizes in the monoclinic space group C2/c with Z = 12. The [N 3 HN 3 ] -ion is characterized by an asymmetric N-Hβ’β’β’N hydrogen bridge with a N-N distance of 272 pm. -(NEUMUELLER,