Crystal Structure of a Platinum Complex Containing NCl2 Ligands: [Pt(NH3)3(NCl2)2Cl]Cl

✍ Scribed by Dr. Mathias Zipprich; Dr. Hans Pritzkow; Prof. Dr. Jochen Jander

• Publisher: John Wiley and Sons
• Year: 1976
• Tongue: English
• Weight: 239 KB
• Volume: 15
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.197602251

✦ Synopsis

spectra. The broad resonance (8TMS= 37.6 ppm) observed at +27"C for C-10 and C-12 became a sharp singlet when the temperature was increased to +40°C and also when it was ~decreased to -20°C. At low temperatures no signal was Med. Chem. 6; 130 (1963) Table 2. Calculated strain energies of various conformations of the hydrocarbon ( 1 ). The following energy terms have been used: E , (bond length strain), €0 (angle strain), E+ (torsional strain), €6 (out-of-plane strain in aromatic rings), En, (non-bonded interactional strain). Total strain energy, E , = €, + €8 + E+ + €6 +En,. For force constants and other empirical parameters, see Refs. [7] and [8].

C ( 3 )

-91.8