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Synthesis and Structure of [(C5Me5)2Rh2S8], a Dirhodium Complex with Unusual Polysulfide Bridge

✍ Scribed by Prof. Dr. Henri Brunner; Norbert Janietz; Walter Meier; Dr. Bernd Nuber; Dr. Joachim Wachter; Prof. Dr. Manfred L. Ziegler

Publisher: John Wiley and Sons
Year: 1988
Tongue: English
Weight: 249 KB
Volume: 27
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.198807081

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✦ Synopsis

a) Space group P2,2,2,, a=S.975(5), b=8.67(1), c= 17.32(2) A, V=897 A' , Z = 4 . 789 observed reflections (f>oJ. Two-circle diffractometer, MoKn radiation, 0,-scan, rapid decomposition of the crystals during the measurement. C o and butyne C-atoms anisotropic, the disordered benzene ligand was refined with two rigid C6H, rings (C-C 1.395, C-H 0.95 A) with anisotropic temperature factors for the C atoms, R =0.046. b) Further details of the crystal structure are available on request from the Fachinformationszentrum Energie, Physik, Mathematik GmbH, D-7514 Eggenstein-Leopoldshafen 2 (FRG), on quoting the depository number CSD-52910, the names of the authors, and the journal citation.

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