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Synthesis and Structure of [(C5Me5)2M2Se5]: Formation of a μ,η2-Tetraselenide Ligand at the MM Double Bond of [(C5Me5)2M2(μ-CO)2)] (M Co, Rh)

✍ Scribed by Prof. Dr. Henri Brunner; Walter Meier; Dr. Joachim Wachter; Dr. Bernd Nuber; Prof. Dr. Manfred L. Ziegler

Publisher: John Wiley and Sons
Year: 1986
Tongue: English
Weight: 245 KB
Volume: 25
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.198609071

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✦ Synopsis

65% 13 16 Scheme2. Reactionsof 1 ( X ' , X 2 = O ; a ) , 8 ( X ' , X ' = N -N H -T s ; b ) , 9 ( X ' , X'=N-NNa-Ts; c, d), and 10 ( X , = H , X2=Me--S0,; f). a) Al2O3. b) MeLi, EtzO, 0°C. c) 125°C. d) hv, THF, 20°C. e) Preparative gas chromatography, Carbowax, 160°C. f) KOtBu.

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