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Ligand Extrusion from the As4S4-Cage by [C5Me5(CO)2Mo]2: Formation of (C5Me5)2Mo2(CO)4(μ,η2-As2), C5Me5(CO)2Mo(η3-As3), and (C5Me5)2Mo2As2S3

✍ Scribed by Prof. Dr. Ivan Bernal; Prof. Dr. Henri Brunner; Walter Meier; Heike Pfisterer; Dr. Joachim Wachter; Prof. Dr. Manfred L. Ziegler


Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
236 KB
Volume
23
Category
Article
ISSN
0044-8249

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Reactivity of Ferriophosphaalkene [(η5-C
✍ Lothar Weber; Matthias H. Scheffer; Hans-Georg Stammler; Anja Stammler 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 308 KB

Reaction of equimolar amounts of the ferriophosphaalkene P; M = Al (2a), Ga (3a), In (4a) and E = As; M = Al (2b), Ga (3b), and In (4b). These compounds feature η 1 -coordination [(η 5 -C 5 Me 5 )(CO) 2 FeP=C(NMe 2 ) 2 ] (1a) or the ferrioarsaalkene [(η 5 -C 5 Me 5 )(CO) 2 FeAs=C(NMe 2 ) 2 ] (1b) wi