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[(η5-C5Me5)2Fe2S4] and [(η5-C5Me5)2Co2S4], Two Novel Bis(pentamethylcyclopentadienylmetal) Complexes Rich in Sulfur

✍ Scribed by Prof. Dr. Henri Brunner; Norbert Janietz; Walter Meier; Gertrud Sergeson; Dr. Joachim Wachter; Dipl.-Chem. Thomas Zahn; Prof. Dr. Manfred L. Ziegler

Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
236 KB
Volume
24
Category
Article
ISSN
0044-8249

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Reaction of equimolar amounts of the ferriophosphaalkene P; M = Al (2a), Ga (3a), In (4a) and E = As; M = Al (2b), Ga (3b), and In (4b). These compounds feature η 1 -coordination [(η 5 -C 5 Me 5 )(CO) 2 FeP=C(NMe 2 ) 2 ] (1a) or the ferrioarsaalkene [(η 5 -C 5 Me 5 )(CO) 2 FeAs=C(NMe 2 ) 2 ] (1b) wi