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Synthesis of [(C5Me5)2Mo2XS3Co(CO)2] Clusters (X = P, As) and Structural Characterization of a μ2, η2-AsS Ligand

✍ Scribed by Prof. Dr. Henri Brunner; Dipl.-Chem. Heike Kauermann; Dr. Ulrich Klement; Dr. Joachim Wachter; Dipl.-Chem. Thomas Zahn; Prof. Dr. Manfred L. Ziegler


Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
244 KB
Volume
24
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES


Synthesis and Structure of [(C5Me5)2M2Se
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65% 13 16 Scheme2. Reactionsof 1 ( X ' , X 2 = O ; a ) , 8 ( X ' , X ' = N -N H -T s ; b ) , 9 ( X ' , X'=N-NNa-Ts; c, d), and 10 ( X , = H , X2=Me--S0,; f). a) Al2O3. b) MeLi, EtzO, 0°C. c) 125°C. d) hv, THF, 20°C. e) Preparative gas chromatography, Carbowax, 160°C. f) KOtBu.

Reactivity of Ferriophosphaalkene [(η5-C
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Reaction of equimolar amounts of the ferriophosphaalkene P; M = Al (2a), Ga (3a), In (4a) and E = As; M = Al (2b), Ga (3b), and In (4b). These compounds feature η 1 -coordination [(η 5 -C 5 Me 5 )(CO) 2 FeP=C(NMe 2 ) 2 ] (1a) or the ferrioarsaalkene [(η 5 -C 5 Me 5 )(CO) 2 FeAs=C(NMe 2 ) 2 ] (1b) wi