Synthesis of [(C5Me5)2Mo2XS3Co(CO)2] Clusters (X = P, As) and Structural Characterization of a μ2, η2-AsS Ligand
✍ Scribed by Prof. Dr. Henri Brunner; Dipl.-Chem. Heike Kauermann; Dr. Ulrich Klement; Dr. Joachim Wachter; Dipl.-Chem. Thomas Zahn; Prof. Dr. Manfred L. Ziegler
- Publisher
- John Wiley and Sons
- Year
- 1985
- Tongue
- English
- Weight
- 244 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
65% 13 16 Scheme2. Reactionsof 1 ( X ' , X 2 = O ; a ) , 8 ( X ' , X ' = N -N H -T s ; b ) , 9 ( X ' , X'=N-NNa-Ts; c, d), and 10 ( X , = H , X2=Me--S0,; f). a) Al2O3. b) MeLi, EtzO, 0°C. c) 125°C. d) hv, THF, 20°C. e) Preparative gas chromatography, Carbowax, 160°C. f) KOtBu.
Reaction of equimolar amounts of the ferriophosphaalkene P; M = Al (2a), Ga (3a), In (4a) and E = As; M = Al (2b), Ga (3b), and In (4b). These compounds feature η 1 -coordination [(η 5 -C 5 Me 5 )(CO) 2 FeP=C(NMe 2 ) 2 ] (1a) or the ferrioarsaalkene [(η 5 -C 5 Me 5 )(CO) 2 FeAs=C(NMe 2 ) 2 ] (1b) wi