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Synthesis and Structure of [(C5Me5)2Mo2S4·SO3]: Concerning the Oxidation of Sulfur Ligands in Transition-Metal Complexes

✍ Scribed by Prof. Dr. Henri Brunner; Dr. Ulrich Klement; Joachim Pfauntsch; Dr. Joachim Wachter


Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
262 KB
Volume
26
Category
Article
ISSN
0044-8249

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The yellow-orange boratabenzene complex Cb\*Co(3,5-Me 2 C 5 H 3 BNMe 2 ) (1) (Cb\* = C 4 Me 4 ) was readily obtained from [Cb\*Co(NCMe) 3 ]PF 6 and Li(TMEDA)(3,5-Me 2 C 5 H 3 BNMe 2 ). Methanolysis of 1 afforded Cb\*Co(3,5-Me 2 C 5 H 3 BOMe) (2). Complex 2 reacted with MeLi and with BCl 3 to give th