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Synthesis and Structure of [NbCl3{[NPPh2(C5H4)]2Fe}]: The First Structurally Characterised Complex Containing a Chelating Di(phosphaneiminato) Ligand

✍ Scribed by Ulrich Siemeling; Beate Neumann; Hans-Georg Stammler; Oliver Kuhnert

Publisher: John Wiley and Sons
Year: 2000
Tongue: German
Weight: 72 KB
Volume: 626
Category: Article
ISSN: 0372-7874
DOI: 10.1002/(sici)1521-3749(200004)626:4<825::aid-zaac825>3.0.co;2-v

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✦ Synopsis

Reaction of [Fe{(C 5 H 4 )PPh 2 =NSiMe 3 } 2 ] with niobium pentachloride affords the chelate complex [NbCl 3 {[NPPh 2 (C 5 H 4 )] 2 Fe}].

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