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The First Alkaline Earth Metal Complex Containing a μ-η1:η1 Allyl Ligand: Structure of [{HC[C(tBu)NC6H3(CHMe2)2]2Mg(C3H5)}6]

✍ Scribed by Philip J. Bailey; Stephen T. Liddle; Carole A. Morrison; Simon Parsons

Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 124 KB
Volume: 113
Category: Article
ISSN: 0044-8249
DOI: 10.1002/1521-3757(20011203)113:23<4595::aid-ange4595>3.0.co;2-x

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✦ Synopsis

4595

rolo [2,3-b]indole-1,4-diones based on an electrophilic fluorination ± cyclization sequence. We have demonstrated the utility of this procedure by the efficient syntheses of 1 b and 2 b. The biological activities of these alkaloid isosteres will be evaluated and reported subsequently. In addition, we plan to extend application of this new methodology to the synthesis of fluorinated analogues of other indole alkaloids, including himastatin and asperlicin.

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