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Synthesis and Structure of [NbCl3(NPPh2Fc)2]: The First Example of a Complex Containing a Redox-functionalised Phosphaneiminato Ligand

✍ Scribed by Ulrich Siemeling; Anja Stammler; Hans-Georg Stammler; Oliver Kuhnert

Publisher: John Wiley and Sons
Year: 1999
Tongue: German
Weight: 75 KB
Volume: 625
Category: Article
ISSN: 0372-7874
DOI: 10.1002/(sici)1521-3749(199906)625:6<845::aid-zaac845>3.0.co;2-f

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✦ Synopsis

Reaction of Me 3 SiNPPh 2 Fc (Fc = ferrocenyl) with niobium pentachloride affords [NbCl 3 (NPPh 2 Fc) 2 ], whose redox-functionalised phosphaneiminato ligands exhibit remarkably different bend angles at nitrogen according to a crystal structure analysis.

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