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Cleavage of the CN Bond on a Triruthenium Cluster: Synthesis and Structure of a Triruthenium Complex Containing a μ3-Nitrido Ligand

✍ Scribed by Takashi Kawashima; Toshiro Takao; Hiroharu Suzuki


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
136 KB
Volume
118
Category
Article
ISSN
0044-8249

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Reaction of Me 3 SiNPPh 2 Fc (Fc = ferrocenyl) with niobium pentachloride affords [NbCl 3 (NPPh 2 Fc) 2 ], whose redox-functionalised phosphaneiminato ligands exhibit remarkably different bend angles at nitrogen according to a crystal structure analysis.