Synthesis and structure of a seven electron triangular cluster complex [Mo3S4Cl3(dppe)2(PEt3]
β Scribed by Jun Mizutani; Hideo Imoto; Taro Saito
- Publisher
- Springer
- Year
- 1995
- Tongue
- English
- Weight
- 592 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1040-7278
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The C D spectra of electrochemically generated ions of (R)-( -)-1 and (S)-( +)-1 were recorded over the potential range 0 to -2200 mV. Figure shows the C D spectra of both enantiomeric forms of 12(oe', which were generated at a stationary potential of = -1600 rnV. ["] (S)-lz'oc) shows a positive A
## Abstract New cluster compounds [H~3~O(Ph~3~PO)~3~]~2~[Mo~6~Cl~14~] (I) and [H(Ph~3~PO)~2~]~2~[Re~6~S~6~Br~8~] (II) have been prepared by the reaction of a acetonitrile solution of triphenylphosphane oxide Ph~3~PO with octahedral cluster complexes of molybdenum (H~3~O)~2~Mo~6~Cl~14~Β·6H~2~O and rh
The complex of (Me 4 N) 2 Mo 3 S 13 (I) has been synthesized under mild hydrothermal condition. The crystal structure was determined by single crystal X-ray diffraction at room temperature. Crystal data: M = 854.91, Trigonal, space group P3 (No. 143), a = 11.2351(8) Γ , c = 5.8885(6) Γ , and Z = 1, Th