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Synthesis, Structural Characterization and Reactivity of Two New Triangular Molybdenum Cluster Compounds: Mo3Te7-[S2CN(CH2CH2OH)2]3I and Mo3Te4Y3[S2P(iPrO)2]3I (Y3 = 1.43Te + 1.57S)

✍ Scribed by Wen-Bin Yang; Xiang Lin; Can-Zhong Lu; Hong-Hui Zhuang


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
615 KB
Volume
20
Category
Article
ISSN
0256-7660

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Synthesis and Structural Characterizatio
✍ Jin Chen; Shao-Fang Lu; Zi-Xiang Huang; Rong-Min Yu; Qiang-Jin Wu 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 157 KB 👁 2 views

Reaction of [Mo 3 Y(m-S) 3 (dtp) 4 (H 2 O)] (Y O, S; dtp S 2 P(OC 2 H 5 ) 2 À ) with HgI 2 gave the novel compound {[Mo 3 S 7 (dtp) 3 ] 4 ´I}{(HgI 3 ) 3 } ´4 H 2 O (1), which contains a {[Mo 3 S 7 (dtp) 3 ] 4 ´I} tetramer and (HgI 3 ) À . Compound 1 has been characterized by IR, Raman, UV/Vis, and N