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Synthesis and Structural Characterization of the Novel Cluster Compound {[Mo3S7(dtp)3]4⋅I}{(HgI3)3}⋅4 H2O (dtp=S2P(OC2H5)2−)

✍ Scribed by Jin Chen; Shao-Fang Lu; Zi-Xiang Huang; Rong-Min Yu; Qiang-Jin Wu

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
157 KB
Volume
7
Category
Article
ISSN
0947-6539

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✦ Synopsis

Reaction of [Mo 3 Y(m-S) 3 (dtp) 4 (H 2 O)] (Y O, S; dtp S 2 P(OC 2 H 5 ) 2 À ) with HgI 2 gave the novel compound {[Mo 3 S 7 (dtp) 3 ] 4 ´I}{(HgI 3 ) 3 } ´4 H 2 O (1), which contains a {[Mo 3 S 7 (dtp) 3 ] 4 ´I} tetramer and (HgI 3 ) À . Compound 1 has been characterized by IR, Raman, UV/Vis, and NMR spectroscopy and single-crystal X-ray diffraction analysis. It is shown that this formation process can be referred to as a new cluster reaction. The structure and spectroscopic data of the tetramer is also compared with that of the related discrete cluster [Mo 3 S 7 (dtp) 3 ´I]. Crystal data: space group F23, a 26.786(3) , V 19218.7(4) 3 , Z 4, R 0.059.

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