Reaction of [Mo 3 Y(m-S) 3 (dtp) 4 (H 2 O)] (Y O, S; dtp S 2 P(OC 2 H 5 ) 2 À ) with HgI 2 gave the novel compound {[Mo 3 S 7 (dtp) 3 ] 4 ´I}{(HgI 3 ) 3 } ´4 H 2 O (1), which contains a {[Mo 3 S 7 (dtp) 3 ] 4 ´I} tetramer and (HgI 3 ) À . Compound 1 has been characterized by IR, Raman, UV/Vis, and N
✦ LIBER ✦
Small Gold Clusters with Carborane Ligands: Synthesis and Structural Characterization of the Novel Compound [Au4{(PPh2)2C2B9H10}2(AsPh3)2]
✍ Scribed by Dr. Olga Crespo; Dr. M. Concepión Gimeno; Prof. Dr. Peter G. Jones; Prof. Dr. Antonio Laguna; Dr. M. Dolores Villacampa
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 412 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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The first examples of g 1 -complexes of 1,2,4-triphospholes are reported in which the ring acts as a 2e and a 4e donor.