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Synthesis and Structure of the Novel Ga3P3 Ring Compound [(2,4,6-Ph3C6H2)GaP(cyclo-C6H11)]3

✍ Scribed by Professor Håkon Hope; Doris C. Pestana; Professor Philip P. Power

Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
386 KB
Volume
30
Category
Article
ISSN
0044-8249

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Reaction of elemental antimony with sulfur under mild hydrothermal conditions yielded different polysulfidoclusters of antimony. These were isolated as tetraphenylphosphonium salts [P(C 6 H 5 ) 4 ] 3 Sb 3 S 25 and [P(C 6 H 5 ) 4 ] 2 Sb 2 S 15 2(C 3 N 2 H 6 ) and their crystal structures were determi