𝔖 Bobbio Scriptorium
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Syntheses and structures of Tetranuclear Cluster complexes of molybdenum [Mo4(μ3-S)2(μ2-S)4X2-(PMe3)6] (X= SH, Cl, Br, I, SCN) and [Mo4(μ3-S)2-(μ2-S)4(dtc)2(PMe3)4] (dtc = diethyldithiocarbamate)

✍ Scribed by Kiyoshi Tsuge; Setsuko Mita; Hiroko Fujita; Hideo Imoto; Taro Saito


Publisher
Springer
Year
1996
Tongue
English
Weight
850 KB
Volume
7
Category
Article
ISSN
1040-7278

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Isolation of a New Cs-Symmetrized Mo3(μ3
✍ Rita Hernandez-Molina; Javier Gonzalez-Platas; Cristian Vicent 📂 Article 📅 2012 🏛 John Wiley and Sons 🌐 English ⚖ 602 KB

A new cluster of formula {[Mo 3 (μ 3 -S)(μ-S)(μ-S 2 ) 2 (dtp) 3 (μ-OAc)][Mo 3 NiS 4 (dtp) 3 (μ-OAc)(CH 3 CN)]} (1; dtp = diethyl dithiophosphate; OAc = acetate) comprising the novel C s -symmetrized Mo 3 (μ 3 -S)(μ-S)(μ-S 2 ) 2 structural type covalently attached to a cubane-type Mo 3 NiS 4 core has