Synthesis, Structure and Characterizations of a Molybdenum Sulfide Complex with inorganic Cluster [Mo3S13]2- and Organic Amine Me4N+

✍ Scribed by S. Lu; Y. Ke; J. Li; Y. Zhang

• Publisher: John Wiley and Sons
• Year: 2002
• Tongue: English
• Weight: 188 KB
• Volume: 37
• Category: Article
• ISSN: 0232-1300
• DOI: 10.1002/1521-4079(200211)37:11<1153::aid-crat1153>3.0.co;2-4

✦ Synopsis

The complex of (Me 4 N) 2 Mo 3 S 13 (I) has been synthesized under mild hydrothermal condition. The crystal structure was determined by single crystal X-ray diffraction at room temperature. Crystal data: M = 854.91, Trigonal, space group P3 (No. 143), a = 11.2351(8) Å, c = 5.8885(6) Å, and Z = 1, There is an inorganic [Mo 3 S 13 ] 2-core composed of a Mo 3 -triangle, a µ 3 -S atom, three doubly bridging disulfide and three terminal disulfide. Two organic amine ions act as the positive charge to balance the [Mo 3 S 13 ] 2-cluster.