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Synthesis and Structure Determination of [AsPh4] [Ru6H(μOCNMe2)2 (μCO)4(CO)14] Me2CO; A Hydrido-Hexametallic Cyclic Anion

✍ Scribed by Dr. Neil M. Boag; Dr. Carolyn B. Knobler; Prof. Dr. Herbert D. Kaesz

Publisher: John Wiley and Sons
Year: 1983
Tongue: English
Weight: 248 KB
Volume: 22
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.198301980

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✦ Synopsis

W e were interested i n examining s i n g l e c r y s t a l s containing the triruthenium anion I R u ~( ~Y C = ~N ~~) (p-a))3(CO),l-which we obtain q u a n t i t a t i v e l y as t h e quanidinim salt, l a , i n the treatment of R U ~( C O ) ~~ with CfNMe2)4.'1/ When c r y s t a l s of l a proved unsuitable f o r X-ray study we were l e d t o s e e k the ptassium s a l t , l b , by deprotomtion of t h e neutral precursor 2, shown i n reaction (1).

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