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Mono-, Di-, and Trimetallic Complexes of the Nonalternating Polycondensed π-Perimeter Decacyclene, C36H18: Synthesis, Structure, and Spectroelectrochemistry of [{(η5-Me4EtC5)Co}2(μ-η5:η4-C36H18)]

✍ Scribed by Jörg J. Schneider; Dirk Spickermann; Thomas Labahn; Jörg Magull; Marco Fontani; Franco Laschi; Piero Zanello


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
233 KB
Volume
6
Category
Article
ISSN
0947-6539

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The trichlorides of yttrium, samarium, and lutetium react with 2 equivalents of Na[C 5 H 4 t Bu] and 1 equivalent of NaBH 4 to give [(g 5 -C 5 H 4 t Bu) 2 LnBH 4 (THF)] (Ln = Y (1), Sm (2), Lu (3)) or with 2 equivalents of Na[C 5 Me 4 R] and 1 equivalent of NaBH 4 to form [(g 5 -C 5 Me 4 R) 2 ĹnBH 4