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Synthesis and Structure of [AsPh4][Ru6H(μ-OCNMe2)2(μ-CO)4-(CO)14]·Me2CO; A Cyclic Hydrido-Hexametallic Anion

✍ Scribed by Dr. Neil M. Boag; Dr. Carolyn B. Knobler; Prof. Dr. Herbert D. Kaesz

Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
218 KB
Volume
22
Category
Article
ISSN
0044-8249

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Synthesis and Structure Determination of
Synthesis and Structure Determination of [AsPh4] [Ru6H(μOCNMe2)2 (μCO)4(CO)14] Me2CO; A Hydrido-Hexametallic Cyclic Anion
✍ Dr. Neil M. Boag; Dr. Carolyn B. Knobler; Prof. Dr. Herbert D. Kaesz 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 248 KB

W e were interested i n examining s i n g l e c r y s t a l s containing the triruthenium anion I R u ~( ~Y C = ~N ~~) (p-a))3(CO),l-which we obtain q u a n t i t a t i v e l y as t h e quanidinim salt, l a , i n the treatment of R U ~( C O ) ~~ with CfNMe2)4.'1/ When c r y s t a l s of l a proved u