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Synthesis and Structural Characterization of Neutral and Cationic Alkylaluminum Complexes Based on Bidentate Aminophenolate Ligands

✍ Scribed by Dagorne, Samuel; Lavanant, Laurent; Welter, Richard; Chassenieux, Christophe; Haquette, Pierre; Jaouen, Gérard


Book ID
121386878
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
198 KB
Volume
22
Category
Article
ISSN
0276-7333

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Synthesis and Structural Characterizatio
✍ Reisgys, Martina ;Spies, Hartmut ;Johannesn, Bernd ;Pietzsch, Hans-Jergen ;Leibn 📂 Article 📅 1997 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 493 KB 👁 1 views

Neutral oxorhenium(V) complexes with dithioether ligands of the general formula [ReOX3(RS[CHz]2SR)], X = C1, Br, R = nBu, Et, Bzl were synthesized. Ammonium perrhenate reacts in concentrated hydrochloric acid with dithiaalkanes (RS[CH2I2SR, R = nBu, Et, Bzl) dissolved in glacial acetic acid to give