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Synthesis and NMR characterization of cationic rhodium(I) complexes containing phosphorus—sulfur bidentate ligands

✍ Scribed by Carlo Bonuzzi; Mario Bressan; Franco Morandini; Antonino Morvillo

Book ID
108327979
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
257 KB
Volume
154
Category
Article
ISSN
0020-1693

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The synthesis and properties of cationic complexes of general formula [ML2{CH2(Ph2PE)2}]BF4, where M = Pd H and Rh n, L2 = q3-MeC3H4, {P(O)(OR)z}EH (R = Me, Et), COD, (CO)z, (CO)PPh 3 and E = S, Se are described. The methylene proton of the coordinated phosphine sulphide or selenide ligands react wi