Preparation and properties of palladium(
β
RaΓΊl Contreras; Mauricio Valderrama; Sandra A.
π
Article
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1993
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Springer
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English
β 454 KB
The synthesis and properties of cationic complexes of general formula [ML2{CH2(Ph2PE)2}]BF4, where M = Pd H and Rh n, L2 = q3-MeC3H4, {P(O)(OR)z}EH (R = Me, Et), COD, (CO)z, (CO)PPh 3 and E = S, Se are described. The methylene proton of the coordinated phosphine sulphide or selenide ligands react wi