## Abstract The __ortho__βpalladation of the iminophosphane ligand 6βphenylβ2β[(2,6βdiisopropylphenyl)imino]pyridine (HL) with Pd(OAc)~2~ and PdCl~2~(PhCN)~2~ in benzene yields the neutral PdβC,N,N pincer complexes Pd(OAc)(ΞΊ^3^βC,N,NβL) (1) and PdCl(ΞΊ^3^βC,N,NβL) (2), respectively. In the presence
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Neutral and Cationic Methylaluminium Complexes of 2-Anilinotropone Ligands: Synthesis, Characterization, and Reactivity toward Ethylene
β Scribed by Daniela Pappalardo; Mina Mazzeo; Pasquale Montefusco; Consiglia Tedesco; Claudio Pellecchia
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 148 KB
- Volume
- 2004
- Category
- Article
- ISSN
- 1434-1948
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The organorhodium(I) complexes [Rh(PNP)R] [PNP = 2,6-stable monohydridorhodium(III) complex [Rh(PNP)ClH-(CH 3 CN)]SO 3 CF 3 (7) was obtained by the reaction of bis(diphenylphosphanylmethyl)pyridine, R = CH 3 (3a), C 6 H 5 (3b)] were synthesized from [Rh(PNP)(C 2 H 4 )]BF 4 (1a) and LiR [Rh(PNP)Cl] w