Synthesis and Structural Characterization of a New Open-Framework Tin(II) Phosphate: [Sn 4 (PO 4 ) 3 ] - ·0.5[C 4 N 2 H 12 ] 2+
✍ Scribed by Liu, Yun-Ling; Zhu, Guang-Shan; Chen, Jie-Sheng; Na, Li-Yan; Hua, Jia; Pang, Wen-Qin; Xu, Ru-Ren
- Book ID
- 126993689
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 55 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0020-1669
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
The synthesis and structure of a new tin(II) phosphatooxalate, Sn 2 (PO 4 )[C 2 O 4 ] 0.5 , containing one-dimensional tin phosphate chains are presented. The structure comprises a network of pyramidal SnO 3 , truncated square, pyramidal SnO , and tetrahedral PO 4 moieties which gives rise to one-di
A new layered tin(II) phosphate [Sn 2 (PO 4 ) 2 ] 2؊ [C 2 N 2 H 10 ] 2؉ • H 2 O was synthesized by hydrothermal technique. It crystallizes in monoclinic space group P2 1 /c (No. 14) with lattice parameters a ؍ 9.4112(1) A s ; b ؍ 8.5998(1) A s ; c ؍ 15.9921(2) A s ; ؍ 100.009(1)°; V ؍ 12
enforce an increase in the charge separation. However, whether an 0x0 ligand is sufficiently voluminous to have this steric effect is debatable, and calculations are currently underway to resolve this question." ' 1 Although the greater thermodynamic stability of the trans alcohol with respect to th