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ChemInform Abstract: Syntheses and Crystal Structures of Two New Open-Framework Tin(II) Phosphates: Sn5O2(PO4)2 and Sn4O(PO4)2.

✍ Scribed by Le-Qing Fan; Ji-Huai Wu; Yun-Fang Huang

Publisher
John Wiley and Sons
Year
2008
Weight
25 KB
Volume
39
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

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## Abstract Tin(II) methoxide reacts with __N__,__N__′‐dimethylaminoethanol (dmaeH) to yield Sn(dmae)~2~ (1) along with small amounts of the hydrolysis product Sn~6~(O)~4~(dmae)~4~ (2). The geometrically more regular iso‐structural cage Sn~6~(O)~4~(OEt)~4~ (3) was obtained as the only tractable pro