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Tin(II) aminoalkoxides and heterobimetallic derivatives: the structures of Sn6(O)4(dmae)4, Sn6(O)4(OEt)4 and [Sn(dmae)2Cd(acac)2]2

✍ Scribed by Nathan Hollingsworth; Graeme A. Horley; Muhammed Mazhar; Mary F. Mahon; Kieran C. Molloy; Peter W. Haycock; Christopher P. Myers; Gary W. Critchlow

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
212 KB
Volume
20
Category
Article
ISSN
0268-2605

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✦ Synopsis

Abstract

Tin(II) methoxide reacts with N,N′‐dimethylaminoethanol (dmaeH) to yield Sn(dmae)~2~ (1) along with small amounts of the hydrolysis product Sn~6~(O)~4~(dmae)~4~ (2). The geometrically more regular iso‐structural cage Sn~6~(O)~4~(OEt)~4~ (3) was obtained as the only tractable product isolated from reaction of 2 and Sb(OEt)~3~, while 1 reacted with CdX~2~ (X = acac, I) to afford Sn(dmae)~2~Cd(acac)~2~ (4) and Sn(dmae)~2~CdI~2~ (5). The X‐ray structures of 2, 3 and 4 are reported. Decomposition of 4 under aerosol‐assisted chemical vapour deposition conditions leads to amorphous tin oxide films with no detectable cadmium (i.e. ca < 2% cadmium), rather than a stoichiometric Sn:Cd oxide. Copyright © 2006 John Wiley & Sons, Ltd.

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