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ChemInform Abstract: Synthesis and Structure of the Bicyclic [Sn4Se11]6- Anion in Na6Sn4Se11×22H2O.

✍ Scribed by A. Loose; W. S. Sheldrick

Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 32
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200147023

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Synthesis and Structure of the Bicyclic [Sn4Se11]6– Anion in Na6Sn4Se11 · 22 H2O

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Na 6 Sn 4 Se 11 ´22 H 2 O can be crystallised at ±8 °C as yellow-orange needles from the 1 : 2 H 2 O/CH 3 OH mother liquor of a superheated reaction mixture of NaOH(s), Sn and Se. The bicyclic [Sn 4 Se 11 ] 6± anion exhibits crystallographic C 2 symmetry and is composed of corner-bridged SnSe 4 tetr

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ChemInform Abstract: Synthesis and Structure of [Sn4Se11]6-, ∞1[Sn2Se52-], and ∞1[Sn3Se72-] — Model Anions for the Solventothermal Reaction Pathway to Lamellar Selenidostannates(IV).

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ChemInform Abstract: Solventothermal Synthesis of the Lamellar Selenidostannates(IV) A2Sn4Se9×H2O (A: Rb, Cs) and Cs2Sn2Se6.

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Syntheses, Crystal Structures, and Reactivity of [enH]4[Sn2Se6]×en, [enH]4[Sn2Te6]×en and [enH]4[Sn2S6]: Known Anions within Novel Coordination Spheres Obtained by Novel Synthesis Routes.

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ChemInform Abstract: Na6ZnSn2, Na4.24K1.

ChemInform Abstract: Na6ZnSn2, Na4.24K1.76(1)ZnSn2, and Na20Zn8Sn11: Three Intermetallic Structures Containing the Linear {Sn—Zn—Sn}6- Unit.

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