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ChemInform Abstract: Selenidostannates. Part 1. Synthesis, Structure, and Properties of [Sn2Se6]4-, [Sn4Se10]4-, and [Sn3Se7]2-.

โœ Scribed by Andreas Fehlker; Roger Blachnik


Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
32
Category
Article
ISSN
0931-7597

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Synthesis and Structure of the Bicyclic
โœ A. Loose; W. S. Sheldrick ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 74 KB ๐Ÿ‘ 1 views

Na 6 Sn 4 Se 11 ยด22 H 2 O can be crystallised at ยฑ8 ยฐC as yellow-orange needles from the 1 : 2 H 2 O/CH 3 OH mother liquor of a superheated reaction mixture of NaOH(s), Sn and Se. The bicyclic [Sn 4 Se 11 ] 6ยฑ anion exhibits crystallographic C 2 symmetry and is composed of corner-bridged SnSe 4 tetr