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Synthesis and Structure of a Tin(II) Phosphatooxalate, Sn2(PO4)[C2O4]0.5, Containing One-Dimensional Tin Phosphate Chains

✍ Scribed by Srinivasan Natarajan

Publisher: Elsevier Science
Year: 1998
Tongue: English
Weight: 360 KB
Volume: 139
Category: Article
ISSN: 0022-4596
DOI: 10.1006/jssc.1998.7774

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✦ Synopsis

The synthesis and structure of a new tin(II) phosphatooxalate, Sn 2 (PO 4 )[C 2 O 4 ] 0.5 , containing one-dimensional tin phosphate chains are presented. The structure comprises a network of pyramidal SnO 3 , truncated square, pyramidal SnO , and tetrahedral PO 4 moieties which gives rise to one-dimensional tin phosphate chains separated by the oxalate groups. These linkages create Sn-O-Sn bonding in this structure. 1998

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