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Synthesis and Redox-Induced Structural Isomerization of the Pentagonal Bipyramidal Complexes [W(CN)5(CO)2]3− and [W(CN)5(CO)2]2−

✍ Scribed by Hemamala I. Karunadasa; Jeffrey R. Long


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
398 KB
Volume
121
Category
Article
ISSN
0044-8249

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Heterometallic Nitrido-Carbonyl Clusters
✍ Roberto Della Pergola; Massimiliano Branchini; Alessandro Fumagalli; Luigi Garla 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 326 KB 👁 2 views

The anionic clusters [Fe 5 MN(CO) 14 Cp] 2-[M = Mo (1) or W (2)] were synthesized from [Fe 4 N(CO) 12 ] -and [MCp(CO) 3 ] - in refluxing acetonitrile. The clusters [Fe 3 M 3 N(CO) 18 ] 3-[M = Mo (3) or W (4)] were prepared by reaction of [Fe 4 N(CO) 12 ] - with [M 2 (CO) 10 ] 2-under the same condit