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The Synthesis and Catalytic Properties of Some Open-Sided Binuclear Complexes of RhI: The Structure of [Rh2(CO)2(CH3CN)2{CH(PPh2)3}](CF3SO3)2

✍ Scribed by Hani El-Amouri; Dr. Ali A. Bahsoun; Prof. Jean Fischer; Prof. John A. Osborn


Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
353 KB
Volume
26
Category
Article
ISSN
0044-8249

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Difluoromethylation of Amines with Zn(CF
✍ S. V. Pasenok; N. V. Kirij; Yu. L. Yagupolskii; D. Naumann; W. Tyrra; A. Fitzner πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 German βš– 93 KB πŸ‘ 1 views

The reactions of Zn(CF 3 )Br Β΄2 CH 3 CN, Cd(CF 3 ) 2 Β΄2 CH 3 CN or Bi(CF 3 ) 3 /AlCl 3 with tertiary amines lead to the formation of quaternary ammonium salts of the general formula [R 3 NCF 2 H]X. The reaction of 4-N,N-dimethylaminopyridine with Zn(CF 3 )Br Β΄2 CH 3 CN yields (Ndifluoromethyl)-4-N,N