Synthesis and Reactivity of Z and E Functionalized Allylic Fluorides.
β Scribed by Michael Prakesch; Danielle Gree; Rene Gree
- Book ID
- 101957146
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 178 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
An efficient synthesis of (Z)-allylic trichloroacetimidates starting fi'om lactol 1 is' described. Thermal [3,3] rearrangement of these imidates occurred with excellent chimlity transjkr to give allylic amides.
Stereohomogeneous (E)-and (Z) -crotyltrifluorosilanes were prepared and used for the highly diastereoselective synthesis of threo-and erythro-/?-methylhomoallyl alcohols, respectively, from aldehydes in the presence of fluoride ions. The mechanism of the reaction was discussed. Recently, we have re
## Abstract A new methodology for the enantioselective synthesis of allylic fluorides is developed.