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Synthesis and reactivity of E,Z butadiene-iron tricarbonyl complexes.

✍ Scribed by J Morey; D Grée; P Mosset; L Toupet; R Grée

Book ID
108382986
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
220 KB
Volume
28
Category
Article
ISSN
0040-4039

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(2-Stannylated butadiene) tricarbonyl ir
(2-Stannylated butadiene) tricarbonyl iron complexes: Practical reagents for the synthesis of 2-acyldienes
✍ Pierre-Jean Colson; Michel Franck-Neumann; Madjid Sedrati 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 237 KB

A new route to the stable (2-acylbutadiene) tricarbonyl iron complexes is described, based on the palladium catalyzed coupling between acid chlorides and 2-stannylated butadiene complexes . Conjugated dienes bearing an electron-withdrawing group in position 2 are very reactive derivatives which are