✦ LIBER ✦

Synthesis and rearrangement of (Z)-allylic trichloroacetimidates

✍ Scribed by Catherine Martin; Michel Bortolussi; Robert Bloch

Book ID: 104261409
Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 106 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)00626-7

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✦ Synopsis

An efficient synthesis of (Z)-allylic trichloroacetimidates starting fi'om lactol 1 is' described. Thermal [3,3] rearrangement of these imidates occurred with excellent chimlity transjkr to give allylic amides.

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