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Synthesis and Reactivity of Nickel Hydride Complexes of an α-Diimine Ligand

✍ Scribed by Dong, Qingsong; Zhao, Yanxia; Su, Yuanting; Su, Ji-Hu; Wu, Biao; Yang, Xiao-Juan


Book ID
120367570
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
526 KB
Volume
51
Category
Article
ISSN
0020-1669

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Reaction of (1,2-dimethoxyethane)NiBr 2 a with b-iminoamines ligands c-f is reported and produces a series of paramagnetic complexes (b-diimine)NiBr 2 1c-f. Reduction in situ of compounds 1c-f in the presence of 2-methylallyloxyphosphonium salt 2 was found as a one-step synthesis of nickel allyl cat