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Nickel Complexes with Two Types of Noninnocent Ligands: α-Diimine and Phenazine

✍ Scribed by Dong, Qingsong; Su, Ji-Hu; Gong, Shida; Li, Qian-Shu; Zhao, Yanxia; Wu, Biao; Yang, Xiao-Juan

Book ID
121182464
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
586 KB
Volume
32
Category
Article
ISSN
0276-7333

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Polymerization with TMA-protected polar
Polymerization with TMA-protected polar vinyl comonomers. II. Catalyzed by nickel complexes containing α-diimine-type ligands
✍ Sandra G. Correia; Maria M. Marques; José R. Ascenso; Alejandro F. G. Ribeiro; P 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 160 KB 👁 1 views

␣-Diimine Ni complexes (7, 8) were used as catalyst precursors with MAO in co-and terpolymerization of ethylene/propylene/␣-olefins with OH and COOH functional groups. Trimethylaluminium was used to protect the functional group of polar monomers. The presence of 5-hexen-1-ol seems to have no effect