𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis and structure of cationic nickel allyl complexes supported by β-diimine ligands

✍ Scribed by Kamel Landolsi; Mohamed Rzaigui; Faouzi Bouachir

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
212 KB
Volume
43
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Reaction of (1,2-dimethoxyethane)NiBr 2 a with b-iminoamines ligands c-f is reported and produces a series of paramagnetic complexes (b-diimine)NiBr 2 1c-f. Reduction in situ of compounds 1c-f in the presence of 2-methylallyloxyphosphonium salt 2 was found as a one-step synthesis of nickel allyl cationic complexes 3c-f supported by b-diimine ligands. These compounds are diamagnetic, and have been characterized by NMR and IR spectroscopic data. The structure of cationic nickel complex 3d was solved by X-ray diffraction methods.

📜 SIMILAR VOLUMES

Characterization of the structure and re
Characterization of the structure and reactivity of monocopper–oxygen complexes supported by β-diketiminate and anilido-imine ligands
✍ Benjamin F. Gherman; William B. Tolman; Christopher J. Cramer 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 404 KB 👁 1 views

## Abstract Copper–oxygen complexes supported by β‐diketiminate and anilido‐imine ligands have recently been reported (Aboelella et al., J Am Chem Soc 2004, 126, 16896; Reynolds et al., Inorg Chem 2005, 44, 6989) as potential biomimetic models for dopamine β‐monooxygenase (DβM) and peptidylglycine