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Well-Defined Cationic Methallyl α-Keto-β-Diimine Complexes of Nickel

✍ Scribed by Jason D. Azoulay; Zachary A. Koretz; Guang Wu; Prof. Dr. Guillermo C. Bazan


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
853 KB
Volume
49
Category
Article
ISSN
0044-8249

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Synthesis and structure of cationic nick
✍ Kamel Landolsi; Mohamed Rzaigui; Faouzi Bouachir 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 212 KB

Reaction of (1,2-dimethoxyethane)NiBr 2 a with b-iminoamines ligands c-f is reported and produces a series of paramagnetic complexes (b-diimine)NiBr 2 1c-f. Reduction in situ of compounds 1c-f in the presence of 2-methylallyloxyphosphonium salt 2 was found as a one-step synthesis of nickel allyl cat