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Synthesis and Electrochemical Studies of Nickel β-Diketonate Complexes Incorporating Asymmetric Diimine Ligands

✍ Scribed by Harding, Phimphaka; Harding, David J.; Soponrat, Nitisastr; Tinpun, Kittiya; Samuadnuan, Sirirat; Adams, Harry

Book ID
111687654
Publisher
Commonwealth Scientific and Industrial Research Organisation Publishing
Year
2010
Tongue
English
Weight
589 KB
Volume
63
Category
Article
ISSN
0004-9425

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✍ Kamel Landolsi; Mohamed Rzaigui; Faouzi Bouachir 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 212 KB

Reaction of (1,2-dimethoxyethane)NiBr 2 a with b-iminoamines ligands c-f is reported and produces a series of paramagnetic complexes (b-diimine)NiBr 2 1c-f. Reduction in situ of compounds 1c-f in the presence of 2-methylallyloxyphosphonium salt 2 was found as a one-step synthesis of nickel allyl cat