Synthesis and radical polymerization of 1,1,2,2-tetracyanocyclopropylstyrene
β Scribed by Ju-Yeon Lee; H. K. Hall
- Publisher
- Springer
- Year
- 1990
- Tongue
- English
- Weight
- 255 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0170-0839
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π SIMILAR VOLUMES
A monomer having dibenzothiophene moiety, 2-vinyldibenzothiophene (1), was prepared by the Ni-catalyzed cross-coupling reaction of vinyl bromide with the Grignard reagent of 2-bromodibenzothiophene. The radical homopolymerization of 1 and the copolymerization with styrene were carried out at 60ΠC in
1,3-Bis[(1-alkoxycarbonyl-2-vinylcyclopropane-1-yl)carboxy]benzenes 1 [RO: CH 3 O (a), C 2 H 5 O (b)] were synthesized by the esterification of the corresponding 1-alkoxycarbonyl-2-vinylcyclopropane-1-carboxylic acids with resorcinol. The structure of the new vinylcyclopropanes was confirmed by elem
## Abstract Atom transfer radical polymerization (ATRP) of (__R__)β2βmethacryloyloxyβ2β²βmethoxyβ1,1β²βbinaphthalene ((__R__)βMAMBN) mediated by different amine ligands, copper(I) chloride and ethyl 2βbromopropionate in different solvents, and reverse ATRP of (__R__)βMAMBN were studied. It was shown