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Radical ring-opening polymerization behavior of 1,1-disubstituted-2-vinylcyclopropanes

✍ Scribed by Takeshi Endo; Makoto Watanabe; Katsufumi Suga; Tsutomu Yokozawa

Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
180 KB
Volume
27
Category
Article
ISSN
0887-624X

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πŸ“œ SIMILAR VOLUMES

Radical ring-opening emulsion polymeriza
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Radical emulsion polymerizations of vinylcyclopropanes, 1,1-bis(ethoxycarbonyl)-2-vinylcyclopropane (ECVCP) and 1,1-dichloro-2-vinylcyclopropane (CVCP) were examined. ECVCP underwent soap-free and soap-in emulsion polymerizations satisfactorily to afford the ring-opened polymer in good yields. Polym

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Synthesis and radical polymerization of novel vinylcyclopropanes; 1-carboethoxy-2-trimethylsilyl-2-vinylcyclopropane (1a) and 1-carboethoxy-2-(1-trimethylsilyl)-vinylcyclopropane (1b), were examined. 1a and 1b were prepared by the coupling reaction of 2-trimethylsilylbutadiene with ethyl diazoacetat