Radical ring-opening polymerization behavior of vinylcyclopropanes derived from dienes and chloroform
โ Scribed by Takeshi Endo; Katsufumi Suga
- Publisher
- John Wiley and Sons
- Year
- 1989
- Tongue
- English
- Weight
- 359 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0887-624X
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Radical emulsion polymerizations of vinylcyclopropanes, 1,1-bis(ethoxycarbonyl)-2-vinylcyclopropane (ECVCP) and 1,1-dichloro-2-vinylcyclopropane (CVCP) were examined. ECVCP underwent soap-free and soap-in emulsion polymerizations satisfactorily to afford the ring-opened polymer in good yields. Polym
Synthesis and radical polymerization of novel vinylcyclopropanes; 1-carboethoxy-2-trimethylsilyl-2-vinylcyclopropane (1a) and 1-carboethoxy-2-(1-trimethylsilyl)-vinylcyclopropane (1b), were examined. 1a and 1b were prepared by the coupling reaction of 2-trimethylsilylbutadiene with ethyl diazoacetat
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