Synthesis and radical polymerization of novel vinylcyclopropanes; 1-carboethoxy-2-trimethylsilyl-2-vinylcyclopropane (1a) and 1-carboethoxy-2-(1-trimethylsilyl)-vinylcyclopropane (1b), were examined. 1a and 1b were prepared by the coupling reaction of 2-trimethylsilylbutadiene with ethyl diazoacetat
Radical ring-opening polymerization behavior of vinylcyclopropane derivatives bearing an ester group
โ Scribed by Takeshi Endo; Makoto Watanabe; Katsufumi Suga; Tsutomu Yokozawa
- Publisher
- John Wiley and Sons
- Year
- 1987
- Tongue
- English
- Weight
- 391 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0887-624X
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๐ SIMILAR VOLUMES
Synthesis and radical ring-opening polymerization of vinylcyclopropane bearing six-membered cyclic acetal moiety, l-vinyl-4,8-dioxaspiro[ 2.5loctane ( l ) , were carried out. 1 was prepared by the reaction of l,l-dichloro-2-vinylcyclopropane and 1,3-propanediol in DMF in the presence of a base. Radi
Syntheses and radical ring-opening polymerizations of vinylcyclopropanone derivertives having cyclic six-membered acetal, exomethylene, and phenyl groups; 1vinyl-6-methylene-4,8-dioxaspiro[2.5]octane ( 2b), 1-vinyl-5,7-dimethyl-6-methylene-4,8-dioxaspiro[2.5]octane ( 2c), 1-vinyl-5-phenyl-4,8-dioxas