Synthesis and radical polymerization of 5-methylene-2,2-dimethyl-1,3-dioxolan-4-one
β Scribed by Toyoharu Miyagawa; Fumio Sanda; Takeshi Endo
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 135 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0887-624X
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π SIMILAR VOLUMES
Carbon black-supported sulfuric acid or BF 3 β Et 2 O-initiated polymerizations of 2-methylene-4,4,5,5-tetramethyl-1,3-dioxolane (1), 2-methylene-4-phenyl-1,3-dioxolane (2), and 2-methylene-4-isopropyl-5,5-dimethyl-1,3-dioxane (3) were performed. 1,2-Vinyl addition homopolymers of 1-3 were produced u
The title compound 1 was allowed to react with catechol, 2,3-dihydroxynaphthalene, tetrabromocatechol, resorcinol, saligenin, and 3,5-di-tert-butylcatechol in the presence of triethylamine to form compounds 4a-4d and 4f. Whereas the catechol derivative 4a, the naphthol derivative 4b, and the tetrabr